Paliotti started working with the Neapolitan composer Roberto De Simone as conductor and composer on productions including : "Carmina Vivianea", "Le tarantelle del rimorso","Populorum Progressio", "Li Turchi viaggiano" ( CD version released on 2003), "L'Opera dei Centosedici" etc. 

On 1995 he wrote "Canto della possibilità di sopravvivere" for the saxophonist Michael Brecker and orchestra.

"Messa per il tempo di guerra" dated 1997, it was performed at the San Pietro a Majella Conservatoire of Naples. 

Between 1999 and 2001, Paliotti conceived a series of compositions for the "I solisti del Teatro San Carlo", which were subsequently collected in a CD produced in 2006, entitled "Musica Obliqua". 

 "Tarantella storta", a cd that will be awarded in Germany and France. The concert with this repertoire visited 12 European countries and was broadcasted by Hessischer Rundfunk in 2002. 

For the 2004 edition of the "Leuciana Festival" he wrote the theatre play in music "Coppola Rossa" that led to the 2006 CD under the same title. 

In the same year, the Benetton Foundation commissioned a work that bore the name “Le Forme di Dioniso”. It was performed by the Quartetto Borciani at the Treviso “Palazzo Bomben”, together with vocalist Gianni Lamagna, with whom Paliotti has an ongoing artistic relationship and for whom he has written numerous pieces. 

Again in the "Leuciana Festival",he worked, as conductor and composer, in the project “Modì Maudits”, with Sergio Rubini, Alessandro Haber, Shawn Monteiro etc. 

In 2007 he wrote the “Variazioni concertanti” for solos and orchestra, after Carlo d’Angiò, first executed in Naples, the same year, at the Teatro Mediterraneo. 

In the same year the Spanish tenor Joaquin Pixan commissioned the cd “Musica entre canto, musica e poesia”, with Paliotti’s originals compositions and arrangements for a quartet of musician by the Opera di Madrid amd the pianist Giovanni Auletta. 

In 2011 he wrote “Concert du Printemps” for two mandolins and orchestra, commissioned by the Festival “Mandolines de Lunel” (France) and executed by Hamilton de Holanda & Mike Marshall. 

“La leggenda di Colapesce” is the title of a ballet in one act, with music and libretto by Paliotti, first represented in Pisa, Teatro Verdi, in may 2013 by the Movimentoinactor dance group. 

Still at the Lunel Festival, in 2014 he presented "Nei mari della luna”for two mandolins and a large orchestra. 

At the Opera de Lyon, in January 2015, the show "Napoli continente" debuted, with Lucilla Galeazzi. 

Also in 2015 he wrote and performed the Cantata "Napoli non è" based on a text by R. De Simone, for the 40th anniversary of Pasolini's death 

From 2016 he collaborates with Marco Beasley with whom he recorded, in duo, the CD "Catari ', Maggio, l'Ammore" (2017). 

In 2020 he writes orchestration of tunes by Debussy, Stravinsky and Satie for the project "Tra scritture e Trascritture" by Roberto De Simone (Naples, Teatro San Carlo).

Again with Beasley he wrote "I o sono una forza del passato" based on  texts by Pasolini, commissioned by the Stresa Festival 2022.

He has realised over forty records, the most relevant ones of which include: "Condannati a vagare sui mari", of 1996, featuring the first recordings of several of Schönberg’s “Brettl-Lieder”, and “La montagna fredda” (2004) containing an eclectic mixture of own compositions, and improvisations on themes taken from the classical Neapolitan tradition. 

Other partnerhips include: Cinema: Roman Coppola, Georg Brintrup, Pappi Corsicato, Antonio Capuano and others. Theatre: Mariano Rigillo, Moni Ovadia, Maurizio Scaparro, Cloris Brosca, Michele Monetta, Alessandro Haber, Ettore Massarese and others. 

As well as: Teatro San Carlo, Art Ensemble of Chicago, I Zezi, ZDF-Artè, Raisat, Torino-Settembre Musica, Piccolo Teatro di Milano, Associazione Scarlatti, Eugenio Bennato and many others.